2-Hydroxyethyl Methacrylate (HEMA) — CAS 868-77-9

Hydroxyethyl Methacrylate (HEMA) is a hydroxy-functional methacrylate monomer widely used in acrylic resins, coatings, adhesives, polymer modification and specialty materials.

HEMA contains both methacrylate double bonds and hydroxyl functionality, providing excellent polymerization reactivity and crosslinking capability.

2-Hydroxyethyl Methacrylate (HEMA) — CAS 868-77-9 product photo

Technical Data Sheet (TDS)

Safety Data Sheet (SDS)

Sample Certificate of Analysis (COA)

Sample COA for reference. Batch-specific COA is issued with each shipment.

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Technical Specifications

CAS: 868-77-9 · EC: 212-782-2 · HS: 2916140000

Formula: C6H10O3 · MW: 130.14 g/mol

Synonyms: HEMA, 2-Hydroxyethyl 2-Methylprop-2-enoate

ParameterValueMethod
Purity (monoester)≥ 97.0% (98% grade also available)GC
Water Content≤ 0.10%Karl Fischer
Acid Value≤ 1.0 mg KOH/gTitration
Color≤ 30 APHAVisual
Inhibitor (MEHQ)Stabilized (custom levels available)HPLC
Density (20°C)Approx. 1.07 g/cm³ASTM D4052

Key Features

  • High purity methacrylate monomer
  • Excellent polymerization performance
  • Hydroxyl functional group for crosslinking
  • Good compatibility with resin systems
  • Stable global supply capability

Applications

UV Curing Coatings

Improves coating adhesion, hardness and crosslinking performance.

Acrylic Resins

Functional monomer for hydroxyl acrylic resin synthesis.

Automotive & Industrial Coatings

Provides durability, weather resistance and chemical resistance.

Adhesives & Sealants

Improves bonding strength and formulation flexibility.

Medical Polymer Materials

Specialty polymer systems requiring hydrophilic properties.

Packaging & Supply

PackagingCapacityUse
Standard Drums200 kg steel or HDPE drumsLCL & FCL container shipments
IBC Totes1,000 kg IBC containersStandard industrial users
Bulk ISO Tank20,000–24,000 kgBulk shipments for large industrial buyers

Storage & Safety

ItemRequirement
Storage Temperature15–25°C in a dry, well-ventilated area away from direct sunlight
Inhibitor & Air BlanketRequires oxygen in the vapor space to maintain MEHQ inhibitor effectiveness; do not store under nitrogen or inert gas
Shelf Life12 months from manufacturing date in unopened original containers
HEMA is classified as a hazardous substance (GHS: Danger — causes severe skin burns and eye damage; may cause allergic skin reaction; toxic in contact with skin). Handle with appropriate personal protective equipment in well-ventilated areas. Refer to the SDS for detailed emergency protocols.

FAQ

What is 2-Hydroxyethyl Methacrylate (HEMA) and what are its main applications?

2-Hydroxyethyl Methacrylate (HEMA) (CAS 868-77-9) is a functional hydroxyl monomer used primarily in automotive coatings, thermosetting acrylic resins, UV-curable inks, adhesives, and specialty polymers.

What packaging sizes are available for export?

We supply HEMA in 200 kg steel/plastic drums, 1,000 kg IBC totes, and ISO tanks for large bulk orders.

What is the shelf life and proper storage condition for HEMA?

The shelf life is 12 months when stored in unopened original containers at 15–25°C in a cool, ventilated area with air blanket presence.